| dc.contributor.author |
Haroutounian, SA |
en |
| dc.contributor.author |
Couladouros, EA |
en |
| dc.date.accessioned |
2014-06-06T06:43:03Z |
|
| dc.date.available |
2014-06-06T06:43:03Z |
|
| dc.date.issued |
1996 |
en |
| dc.identifier.issn |
09473440 |
en |
| dc.identifier.uri |
http://62.217.125.90/xmlui/handle/123456789/978 |
|
| dc.relation.uri |
http://www.scopus.com/inward/record.url?eid=2-s2.0-33749123687&partnerID=40&md5=7f7ed30d45180f5b7add90a61bb90639 |
en |
| dc.subject |
β-Hyrogen transfer |
en |
| dc.subject |
C-Benzylation |
en |
| dc.subject |
Grignard reaction |
en |
| dc.title |
Reaction of 4′-benzyloxy-2-(4-pyridinyl)acetophenone with ethylmagnesium chloride: Unusual C-benzylation and in situ reduction by β-hydrogen transfer |
en |
| heal.type |
journalArticle |
en |
| heal.publicationDate |
1996 |
en |
| heal.abstract |
In solution, 4′-benzyloxy-2-(4-pyridinyl)acetophenone (1) mainly exists as enol 4 which does not undergo typical Grignard addition reactions. Treatment with an excess of ethylmagnesium chloride, however, initiates an unusual sequence of transformations leading to formation of the C-benzylated compounds 2 and 3. © VCH Verlagsgesellschaft mbH, 1996. |
en |
| heal.journalName |
Liebigs Annales |
en |
| dc.identifier.issue |
7 |
en |
| dc.identifier.spage |
1139 |
en |
| dc.identifier.epage |
1141 |
en |