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Development of a rapid method for the quantitative analysis of four methoxypyrazines in white and red wine using multi-dimensional Gas Chromatography - Mass Spectrometry

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dc.contributor.author Botezatu, A en
dc.contributor.author Pickering, GJ en
dc.contributor.author Kotseridis, Y en
dc.date.accessioned 2014-06-06T06:53:01Z
dc.date.available 2014-06-06T06:53:01Z
dc.date.issued 2014 en
dc.identifier.issn 18737072 en
dc.identifier.uri http://dx.doi.org/10.1016/j.foodchem.2014.03.044 en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/6307
dc.subject Dimethyl methoxypyrazin en
dc.subject Methoxypyrazines en
dc.subject Multi dimensional gas chromatography en
dc.subject Wine en
dc.subject.other Gas chromatography en
dc.subject.other Analytical method en
dc.subject.other Dimethyl methoxypyrazin en
dc.subject.other Gaschromatography-mass spectrometry en
dc.subject.other Grape cultivars en
dc.subject.other Limits of detection en
dc.subject.other Methoxypyrazines en
dc.subject.other Multi dimensional en
dc.subject.other Reliable methods en
dc.subject.other Wine en
dc.subject.other pyrazine derivative en
dc.subject.other accuracy en
dc.subject.other article en
dc.subject.other cultivar en
dc.subject.other grape en
dc.subject.other limit of detection en
dc.subject.other mass fragmentography en
dc.subject.other nonhuman en
dc.subject.other quantitative analysis en
dc.subject.other red wine en
dc.subject.other standard en
dc.subject.other white wine en
dc.title Development of a rapid method for the quantitative analysis of four methoxypyrazines in white and red wine using multi-dimensional Gas Chromatography - Mass Spectrometry en
heal.type journalArticle en
heal.identifier.primary 10.1016/j.foodchem.2014.03.044 en
heal.publicationDate 2014 en
heal.abstract Alkyl-methoxypyrazines (MPs) are important odour-active constituents of many grape cultivars and their wines. Recently, a new MP - 2,5-dimethyl-3- methoxypyrazine (DMMP) - has been reported as a possible constituent of wine. This study sought to develop a rapid and reliable method for quantifying DMMP, isopropyl methoxypyrazine (IPMP), secbutyl methoxypyrazine (SBMP) and isobutyl methoxypyrazine (IBMP) in wine. The proposed method is able to rapidly and accurately resolve all 4 MPs in a range of wine styles, with limits of detection between 1 and 2 ng L-1 for IPMP, SBMP and IBMP and 5 ng L -1 for DMMP. Analysis of a set of 11 commercial wines agrees with previously published values for IPMP, SBMP and IBMP, and shows for the first time that DMMP may be an important and somewhat common odorant in red wines. To our knowledge, this is the first analytical method developed for the quantification of DMMP in wine. © 2014 Elsevier Ltd. All rights reserved. en
heal.publisher Elsevier Ltd en
heal.journalName Food Chemistry en
dc.identifier.volume 160 en
dc.identifier.doi 10.1016/j.foodchem.2014.03.044 en
dc.identifier.spage 141 en
dc.identifier.epage 147 en


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