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Flexible and mechanical strain resistant large area SERS active substrates

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dc.contributor.author Singh, JP en
dc.contributor.author Chu, H en
dc.contributor.author Abell, J en
dc.contributor.author Tripp, RA en
dc.contributor.author Zhao, Y en
dc.date.accessioned 2014-06-06T06:51:49Z
dc.date.available 2014-06-06T06:51:49Z
dc.date.issued 2012 en
dc.identifier.issn 20403364 en
dc.identifier.uri http://dx.doi.org/10.1039/c2nr00020b en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/5712
dc.subject.other Bending strain en
dc.subject.other Biological substance en
dc.subject.other Biosensing applications en
dc.subject.other Cost effective en
dc.subject.other Cyclic tensile en
dc.subject.other Flexible substrate en
dc.subject.other In-situ en
dc.subject.other Mechanical strain en
dc.subject.other Oblique-angle deposition en
dc.subject.other Polydimethylsiloxane PDMS en
dc.subject.other Practical method en
dc.subject.other Raman probe en
dc.subject.other SERS enhancement en
dc.subject.other SERS substrate en
dc.subject.other SERS-active substrates en
dc.subject.other Strain conditions en
dc.subject.other Surface enhanced Raman Scattering (SERS) en
dc.subject.other Ethylene en
dc.subject.other Microchannels en
dc.subject.other Polyethylene terephthalates en
dc.subject.other Raman spectroscopy en
dc.subject.other Silicones en
dc.subject.other Silver en
dc.subject.other Tensile strain en
dc.subject.other Substrates en
dc.title Flexible and mechanical strain resistant large area SERS active substrates en
heal.type journalArticle en
heal.identifier.primary 10.1039/c2nr00020b en
heal.publicationDate 2012 en
heal.abstract We report a cost effective and facile way to synthesize flexible, uniform, and large area surface enhanced Raman scattering (SERS) substrates using an oblique angle deposition (OAD) technique. The flexible SERS substrates consist of 1 μm long, tilted silver nanocolumnar films deposited on flexible polydimethylsiloxane (PDMS) and polyethylene terephthalate (PET) sheets using OAD. The SERS enhancement activity of these flexible substrates was determined using 10 -5 M trans-1,2-bis(4-pyridyl) ethylene (BPE) Raman probe molecules. The in situ SERS measurements on these flexible substrates under mechanical (tensile/bending) strain conditions were performed. Our results show that flexible SERS substrates can withstand a tensile strain (ε) value as high as 30% without losing SERS performance, whereas the similar bending strain decreases the SERS performance by about 13%. A cyclic tensile loading test on flexible PDMS SERS substrates at a pre-specified tensile strain (ε) value of 10% shows that the SERS intensity remains almost constant for more than 100 cycles. These disposable and flexible SERS substrates can be integrated with biological substances and offer a novel and practical method to facilitate biosensing applications. © 2012 The Royal Society of Chemistry. en
heal.journalName Nanoscale en
dc.identifier.issue 11 en
dc.identifier.volume 4 en
dc.identifier.doi 10.1039/c2nr00020b en
dc.identifier.spage 3410 en
dc.identifier.epage 3414 en


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