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Sorption of 3, 4-dichloroaniline on four contrasting Greek agricultural soils and the effect of liming

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dc.contributor.author Droulia, FE en
dc.contributor.author Kati, V en
dc.contributor.author Giannopolitis, CN en
dc.date.accessioned 2014-06-06T06:51:27Z
dc.date.available 2014-06-06T06:51:27Z
dc.date.issued 2011 en
dc.identifier.issn 03601234 en
dc.identifier.uri http://dx.doi.org/10.1080/03601234.2011.572506 en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/5526
dc.subject 3,4-dca en
dc.subject Distribution coefficients en
dc.subject Freundlich equation en
dc.subject Soil sorption en
dc.subject Sorption isotherms en
dc.subject.other 3,4-dca en
dc.subject.other Distribution coefficients en
dc.subject.other Freundlich equations en
dc.subject.other Soil sorption en
dc.subject.other Sorption isotherms en
dc.subject.other Adsorption isotherms en
dc.subject.other Biogeochemistry en
dc.subject.other Biological materials en
dc.subject.other Organic compounds en
dc.subject.other Polyvinyl alcohols en
dc.subject.other Soils en
dc.subject.other Sorption en
dc.subject.other Soil pollution en
dc.subject.other 3,4 dichloroaniline en
dc.subject.other 3,4-dichloroaniline en
dc.subject.other aniline derivative en
dc.subject.other calcium derivative en
dc.subject.other calcium oxide en
dc.subject.other oxide en
dc.subject.other pesticide en
dc.subject.other agricultural soil en
dc.subject.other calcareous soil en
dc.subject.other enzyme activity en
dc.subject.other ion exchange en
dc.subject.other isotherm en
dc.subject.other liming en
dc.subject.other pH en
dc.subject.other sandy clay loam en
dc.subject.other soil organic matter en
dc.subject.other soil type en
dc.subject.other sorption en
dc.subject.other adsorption en
dc.subject.other agriculture en
dc.subject.other article en
dc.subject.other chemistry en
dc.subject.other evaluation en
dc.subject.other Greece en
dc.subject.other methodology en
dc.subject.other soil en
dc.subject.other soil pollutant en
dc.subject.other Adsorption en
dc.subject.other Agriculture en
dc.subject.other Aniline Compounds en
dc.subject.other Calcium Compounds en
dc.subject.other Greece en
dc.subject.other Oxides en
dc.subject.other Pesticides en
dc.subject.other Soil en
dc.subject.other Soil Pollutants en
dc.subject.other Greece en
dc.title Sorption of 3, 4-dichloroaniline on four contrasting Greek agricultural soils and the effect of liming en
heal.type journalArticle en
heal.identifier.primary 10.1080/03601234.2011.572506 en
heal.publicationDate 2011 en
heal.abstract Sorption of 3, 4-dichloroaniline (3, 4-DCA) on four typical Greek agricultural soils, with distinct texture, organic matter content andcation exchange capacities, was compared by using sorption isotherms and the parameters calculated from the fitted Freundlichequations. The sorption process of 3, 4-DCA to the soil was completed within 48-72 h. The 3, 4-DCA sorption on all soils was welldescribed by the Freundlich equation and all sorption isotherms were of the L-type. The sandy clay loam soil with the highest organicmatter content and a slightly acidic pH was the most sorptive, whereas the two other soil types, a high organic matter and neutralpH clay and a low organic matter and acidic loam, had an intermediate sorption capacity. A typical calcareous soil with low organicmatter had the lowest sorption capacity which was only slightly higher than that of river sand. The 3, 4-DCA sorption correlated bestto soil organic matter content and not to clay content or cation exchange capacity, indicating the primary role of organic matter.The distribution coefficient (Kd) decreased with increasing initial 3, 4-DCA concentration and the reduction was most pronouncedwith the highly sorptive sandy clay loam soil, suggesting that the available sorption sites of the soils are not unlimited. Liming of thetwo acidic soils (the sandy clay loam and the loam) raised their pH (from 6.2 and 5.3, respectively) to 7.8 and reduced their sorptioncapacity by about 50 %, indicating that soil pH may be the second in importance factor (after organic matter) determining 3, 4-DCAsorption. © Taylor & Francis Group, LLC. en
heal.journalName Journal of Environmental Science and Health - Part B Pesticides, Food Contaminants, and Agricultural Wastes en
dc.identifier.issue 5 en
dc.identifier.volume 46 en
dc.identifier.doi 10.1080/03601234.2011.572506 en
dc.identifier.spage 404 en
dc.identifier.epage 410 en


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