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Analysis of photo-chemical degradation behaviour of polyethylene mulching film with pro-oxidants

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dc.contributor.author Kyrikou, I en
dc.contributor.author Briassoulis, D en
dc.contributor.author Hiskakis, M en
dc.contributor.author Babou, E en
dc.date.accessioned 2014-06-06T06:51:11Z
dc.date.available 2014-06-06T06:51:11Z
dc.date.issued 2011 en
dc.identifier.issn 01413910 en
dc.identifier.uri http://dx.doi.org/10.1016/j.polymdegradstab.2011.09.001 en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/5375
dc.subject Degradation performance en
dc.subject Mechanical performance en
dc.subject Photo-chemical degradation mechanisms en
dc.subject Photodegradable mulching films en
dc.subject Polyethylene with pro-oxidants en
dc.subject UV artificial ageing en
dc.subject.other Agricultural productions en
dc.subject.other Biodegradable material en
dc.subject.other Bioinert en
dc.subject.other Combined effect en
dc.subject.other Commercial applications en
dc.subject.other Controlled laboratories en
dc.subject.other Critical factors en
dc.subject.other Experimental investigations en
dc.subject.other Exposure-time en
dc.subject.other Mechanical performance en
dc.subject.other Natural soils en
dc.subject.other Operational properties en
dc.subject.other Photo-chemical degradation mechanisms en
dc.subject.other Photodegradable mulching films en
dc.subject.other Polyethylene film en
dc.subject.other Pro-oxidants en
dc.subject.other Rapid fragmentation en
dc.subject.other Useful lifetime en
dc.subject.other UV artificial ageing en
dc.subject.other UV- and en
dc.subject.other Agriculture en
dc.subject.other Chemical analysis en
dc.subject.other Films en
dc.subject.other Mechanical properties en
dc.subject.other Oxidants en
dc.subject.other Polyethylenes en
dc.subject.other Soils en
dc.subject.other Thermoplastics en
dc.subject.other Ultraviolet radiation en
dc.subject.other Degradation en
dc.title Analysis of photo-chemical degradation behaviour of polyethylene mulching film with pro-oxidants en
heal.type journalArticle en
heal.identifier.primary 10.1016/j.polymdegradstab.2011.09.001 en
heal.publicationDate 2011 en
heal.abstract It is generally accepted that polyolefins are bioinert. The last years, a new class of photodegradable polyethylene films with pro-oxidants has been developed, exhibiting optimised operational properties in terms of controlled UV and/or thermal ageing leading to an abrupt, predefined to some extent, rapid fragmentation into very small fragments. These photodegradable or fragmentable polyethylene films are promoted in the market for various commercial applications. In some cases, these materials are presented as, or are claimed to be, biodegradable materials. Such materials are already used in agriculture in the form of photodegradable mulching films which become fragmented into small remains after the end of their useful lifetime and are incorporated into the soil. However, it has not been verified yet beyond any doubt, that these remains do in fact biodegrade in natural soil, under what conditions, at which rate and what are their effects in agricultural production, the soil and the environment. An experimental investigation has been carried out focusing on the combined effects of critical factors on the controlled (predefined) photo-chemical degradation of photodegradable mulching LLDPE films with pro-oxidants and the behaviour of their remains in the soil. The analysis of the photo-chemical degradation behaviour presented in this paper was carried out through parallel experiments performed under real field and controlled laboratory conditions. The main factors investigated include materials, exposure time, temperature and UV radiation. © 2011 Elsevier Ltd. All rights reserved. en
heal.journalName Polymer Degradation and Stability en
dc.identifier.issue 12 en
dc.identifier.volume 96 en
dc.identifier.doi 10.1016/j.polymdegradstab.2011.09.001 en
dc.identifier.spage 2237 en
dc.identifier.epage 2252 en


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