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Dynamic rastering surface-enhanced Raman scattering (SERS) measurements on silver nanorod substrates

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dc.contributor.author Abell, JL en
dc.contributor.author Garren, JM en
dc.contributor.author Zhao, Y en
dc.date.accessioned 2014-06-06T06:50:54Z
dc.date.available 2014-06-06T06:50:54Z
dc.date.issued 2011 en
dc.identifier.issn 00037028 en
dc.identifier.uri http://dx.doi.org/10.1366/11-06264 en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/5215
dc.subject AgNPs en
dc.subject AgNRs en
dc.subject Nanoparticles en
dc.subject Oblique angle deposition en
dc.subject SERS en
dc.subject Silver nanorod arrays en
dc.subject Surface-enhanced Raman scattering en
dc.subject Uniform SERS substrates en
dc.subject.other AgNPs en
dc.subject.other AgNRs en
dc.subject.other Oblique-angle deposition en
dc.subject.other SERS en
dc.subject.other SERS substrate en
dc.subject.other Silver nanorod arrays en
dc.subject.other Surface enhanced Raman scattering en
dc.subject.other Coenzymes en
dc.subject.other Nanorods en
dc.subject.other Raman scattering en
dc.subject.other Raman spectroscopy en
dc.subject.other Rotation en
dc.subject.other Silver en
dc.subject.other Surfaces en
dc.subject.other Substrates en
dc.subject.other biotin en
dc.subject.other metal nanoparticle en
dc.subject.other nanotube en
dc.subject.other silver en
dc.subject.other article en
dc.subject.other chemistry en
dc.subject.other methodology en
dc.subject.other Raman spectrometry en
dc.subject.other reproducibility en
dc.subject.other standard en
dc.subject.other Biotin en
dc.subject.other Metal Nanoparticles en
dc.subject.other Nanotubes en
dc.subject.other Reproducibility of Results en
dc.subject.other Silver en
dc.subject.other Spectrum Analysis, Raman en
dc.title Dynamic rastering surface-enhanced Raman scattering (SERS) measurements on silver nanorod substrates en
heal.type journalArticle en
heal.identifier.primary 10.1366/11-06264 en
heal.publicationDate 2011 en
heal.abstract Surface-enhanced Raman spectra of a thiol-modified biotin derivative on oblique-angle-deposited silver nanorod (AgNR) array substrates were measured using both static and rotating rastering methods. We find that the rotating rastering method has a strong tendency to decrease the pointto-point relative standard deviation (RSD) compared to static measurements as well as decrease the effects of cumulative excitation exposure. The AgNR substrates treated with the modified biotin typically demonstrate intra-substrate RSDs of <10%, with an average RSD of ∼3% when the rastering radius r=1 mm. The quantitative studies on the relationship between rastering radius, sampling area, and rastering frequency show that only the rastering radius appears to have significant effect on the measured RSD. Our results demonstrate that under the proper measurement and sample preparation conditions, the Ag nanorod substrates are very uniform. © 2011 Society for Applied Spectroscopy. en
heal.journalName Applied Spectroscopy en
dc.identifier.issue 7 en
dc.identifier.volume 65 en
dc.identifier.doi 10.1366/11-06264 en
dc.identifier.spage 734 en
dc.identifier.epage 740 en


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