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'Gab' generalised equation as a basis for sorption spectral analysis

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dc.contributor.author Blahovec, J en
dc.contributor.author Yanniotis, S en
dc.date.accessioned 2014-06-06T06:50:29Z
dc.date.available 2014-06-06T06:50:29Z
dc.date.issued 2010 en
dc.identifier.issn 12121800 en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/5043
dc.relation.uri http://www.scopus.com/inward/record.url?eid=2-s2.0-77958142484&partnerID=40&md5=4de5f3d6ad586be54d4f296dfcb9ab6a en
dc.subject Activity en
dc.subject Approximation en
dc.subject Food en
dc.subject GAB en
dc.subject Isotherm en
dc.subject Polynomial en
dc.subject Sorption en
dc.subject Spectrum en
dc.subject Water en
dc.subject.other Activity en
dc.subject.other Approximation en
dc.subject.other Food en
dc.subject.other GAB en
dc.subject.other Spectrum en
dc.subject.other Adsorption isotherms en
dc.subject.other Desorption en
dc.subject.other Fruits en
dc.subject.other Gelation en
dc.subject.other Moisture determination en
dc.subject.other Polynomial approximation en
dc.subject.other Spectrum analysis en
dc.subject.other Starch en
dc.subject.other Vegetables en
dc.subject.other Water content en
dc.subject.other Solanum tuberosum en
dc.subject.other Triticum aestivum en
dc.title 'Gab' generalised equation as a basis for sorption spectral analysis en
heal.type journalArticle en
heal.publicationDate 2010 en
heal.abstract The transformed sorption isotherm (represented by the ratio of water activity and moisture content (d.b.) versus water activity) was approximated by polynomials of 2nd-6th order. It is shown that the relative derivative of the transformed equation expresses the deviation of the sorption isotherm from the linear relationship between the moisture content and water activity either to the sorption isotherm of the Lagmuir's type (the positive relative derivative) or to the sorption isotherm of the solution type (the negative relative derivative). The relative derivative plotted versus water activity then serves as a spectral indicator of the prevailing sorption mechanism. Spectral analysis is applied to sorption isotherms of potato and wheat starches and some fruits and vegetables. For starches, the differences in the spectral indicator between resorption and desorption as well as the effect of starch processing (gelatinisation and hydrolysis) on spectral analysis are discussed. The role of spectral analysis in the assessment of the prevailing sorption mechanism (surface vs solution sorption) is demonstrated for fruits and vegetables. en
heal.journalName Czech Journal of Food Sciences en
dc.identifier.issue 5 en
dc.identifier.volume 28 en
dc.identifier.spage 345 en
dc.identifier.epage 354 en


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