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Dynamic sorption of ammonium by sandy soil in fixed bed columns: Evaluation of equilibrium and non-equilibrium transport processes

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dc.contributor.author Jellali, S en
dc.contributor.author Diamantopoulos, E en
dc.contributor.author Kallali, H en
dc.contributor.author Bennaceur, S en
dc.contributor.author Anane, M en
dc.contributor.author Jedidi, N en
dc.date.accessioned 2014-06-06T06:50:13Z
dc.date.available 2014-06-06T06:50:13Z
dc.date.issued 2010 en
dc.identifier.issn 03014797 en
dc.identifier.uri http://dx.doi.org/10.1016/j.jenvman.2009.11.006 en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/4999
dc.subject Ammonium en
dc.subject Breakthrough curves en
dc.subject Dynamic sorption en
dc.subject Hydrus-1D en
dc.subject Modeling en
dc.subject.other ammonia en
dc.subject.other calcium ion en
dc.subject.other magnesium ion en
dc.subject.other adsorption en
dc.subject.other ammonium en
dc.subject.other aqueous solution en
dc.subject.other breakthrough curve en
dc.subject.other cation exchange capacity en
dc.subject.other concentration (composition) en
dc.subject.other experimental study en
dc.subject.other ion exchange en
dc.subject.other laboratory method en
dc.subject.other one-dimensional modeling en
dc.subject.other sandy soil en
dc.subject.other transport process en
dc.subject.other wastewater en
dc.subject.other adsorption kinetics en
dc.subject.other aqueous solution en
dc.subject.other aquifer en
dc.subject.other article en
dc.subject.other concentration (parameters) en
dc.subject.other controlled study en
dc.subject.other flow rate en
dc.subject.other isotherm en
dc.subject.other pollution transport en
dc.subject.other process model en
dc.subject.other quantitative analysis en
dc.subject.other sandy soil en
dc.subject.other soil analysis en
dc.subject.other Tunisia en
dc.subject.other waste water en
dc.subject.other Adsorption en
dc.subject.other Cations en
dc.subject.other Models, Theoretical en
dc.subject.other Quaternary Ammonium Compounds en
dc.subject.other Soil en
dc.subject.other Time Factors en
dc.subject.other Waste Disposal, Fluid en
dc.subject.other Water Movements en
dc.subject.other Water Pollutants en
dc.subject.other Water Purification en
dc.title Dynamic sorption of ammonium by sandy soil in fixed bed columns: Evaluation of equilibrium and non-equilibrium transport processes en
heal.type journalArticle en
heal.identifier.primary 10.1016/j.jenvman.2009.11.006 en
heal.publicationDate 2010 en
heal.abstract The release of excess nitrogen-containing compounds into groundwater is a major concern in aquifer recharge by the Soil Aquifer Treatment (SAT) process. Ammonium (N H4+) is one of the most nocive and common nitrogen compounds in wastewaters. In order to assess the risk of wastewater use for aquifer recharge,N H4+adsorption onto Souhil wadi soil sampled from the SAT pilot plant (Nabeul, Tunisia) was studied using laboratory columns experiments. Several experiments were conducted using aqueous synthetic solutions under different aqueous ammonium concentrations and flow rates. Furthermore, a real wastewater solution was used to test the effect of competitive cations contents on N H4+ adsorption. Afterwards, the Hydrus-1D model was used in inverse mode to simulate the ammonium transport through the Souhil wadi soil. For the synthetic solutions, the adsorbed ammonium amount varied from 1 to 30.7 mg kg-1 for aqueous ammonium concentrations between 4.9 and 36.4 mg L-1. The linear isotherm model was found to be the most suitable for describing this adsorption. The flow rate decrease from 45 to 15 mL min-1 induced an increase in the ammonium adsorption capacity by 49%. Indeed, the lesser the flow rate is, the longer the residence time and the higher the exchange between the aqueous solution and soil matrix. The use of wastewater instead of aqueous synthetic solution decreased about 7 times the Souhil wadi adsorption capacity of ammonium because of its relatively high concentrations of competitive ions such as calcium and magnesium. The use of the Hydrus-1D model showed that the chemical non-equilibrium model was the best to simulate the ammonium transport through the laboratory soil columns. © 2009 Elsevier Ltd. All rights reserved. en
heal.journalName Journal of Environmental Management en
dc.identifier.issue 4 en
dc.identifier.volume 91 en
dc.identifier.doi 10.1016/j.jenvman.2009.11.006 en
dc.identifier.spage 897 en
dc.identifier.epage 905 en


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