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Botanical discrimination and classification of honey samples applying gas chromatography/mass spectrometry fingerprinting of headspace volatile compounds

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dc.contributor.author Aliferis, KA en
dc.contributor.author Tarantilis, PA en
dc.contributor.author Harizanis, PC en
dc.contributor.author Alissandrakis, E en
dc.date.accessioned 2014-06-06T06:50:03Z
dc.date.available 2014-06-06T06:50:03Z
dc.date.issued 2010 en
dc.identifier.issn 03088146 en
dc.identifier.uri http://dx.doi.org/10.1016/j.foodchem.2009.12.098 en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/4953
dc.subject Biomarkers en
dc.subject Botanical discrimination en
dc.subject Botanical origin en
dc.subject Chemometrics en
dc.subject Headspace GC/MS en
dc.subject Honey en
dc.subject Solid-phase microextraction (SPME) en
dc.subject Volatiles en
dc.subject.other aliphatic compound en
dc.subject.other phenol derivative en
dc.subject.other terpenoid derivative en
dc.subject.other article en
dc.subject.other chemical composition en
dc.subject.other chestnut en
dc.subject.other citrus fruit en
dc.subject.other controlled study en
dc.subject.other cotton en
dc.subject.other food analysis en
dc.subject.other food composition en
dc.subject.other Greece en
dc.subject.other honey en
dc.subject.other mass fragmentography en
dc.subject.other partial least squares regression en
dc.subject.other pine en
dc.subject.other plant identification en
dc.subject.other species differentiation en
dc.subject.other thyme en
dc.subject.other Citrus en
dc.subject.other Thymus vulgaris en
dc.title Botanical discrimination and classification of honey samples applying gas chromatography/mass spectrometry fingerprinting of headspace volatile compounds en
heal.type journalArticle en
heal.identifier.primary 10.1016/j.foodchem.2009.12.098 en
heal.publicationDate 2010 en
heal.abstract A validated method for the discrimination and classification of honey samples performing GC/MS fingerprinting of headspace volatile compounds was developed. Combined mass spectra of honey samples originated from different plants and geographical regions of Greece were subjected to orthogonal partial least squares-discriminant analysis™ (OPLS™-DA), soft independent modelling of class analogy (SIMCA), and OPLS™-hierarchical cluster analysis (OPLS™-HCA). Analyses revealed an excellent separation between honey samples according to their botanical origin with the percentage of misclassification to be as low as 1.3% applying OPLS™-HCA. Fragments (m/z) responsible for the observed separation were assigned to phenolic, terpenoid, and aliphatic compounds present in the headspace of unifloral honeys. On the other hand, a variable classification for citrus and thyme honeys according to their geographical origin could be achieved. Results suggested that the developed methodology is robust and reliable for the botanical classification of honey samples, and the study of differences in their chemical composition. © 2010 Elsevier Ltd. All rights reserved. en
heal.journalName Food Chemistry en
dc.identifier.issue 3 en
dc.identifier.volume 121 en
dc.identifier.doi 10.1016/j.foodchem.2009.12.098 en
dc.identifier.spage 856 en
dc.identifier.epage 862 en


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