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Degradation of methamidophos on soultanina grapes on the vines and during refrigerated storage

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dc.contributor.author Athanasopoulos, PE en
dc.contributor.author Pappas, C en
dc.contributor.author Kyriakidis, NV en
dc.contributor.author Thanos, A en
dc.date.accessioned 2014-06-06T06:46:28Z
dc.date.available 2014-06-06T06:46:28Z
dc.date.issued 2005 en
dc.identifier.issn 03088146 en
dc.identifier.uri http://dx.doi.org/10.1016/j.foodchem.2003.10.018 en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/3026
dc.subject.other methamidophos en
dc.subject.other article en
dc.subject.other calculation en
dc.subject.other capillary gas chromatography en
dc.subject.other controlled study en
dc.subject.other decomposition en
dc.subject.other freezing en
dc.subject.other fruit storage en
dc.subject.other grape en
dc.subject.other half life time en
dc.subject.other harvest en
dc.subject.other instrumentation en
dc.subject.other intermethod comparison en
dc.subject.other kinetics en
dc.subject.other mathematical model en
dc.subject.other nonhuman en
dc.subject.other pesticide spraying en
dc.subject.other vineyard en
dc.subject.other Vitaceae en
dc.title Degradation of methamidophos on soultanina grapes on the vines and during refrigerated storage en
heal.type journalArticle en
heal.identifier.primary 10.1016/j.foodchem.2003.10.018 en
heal.publicationDate 2005 en
heal.abstract Decomposition of the pesticide methamidophos was studied in an experiment in field-sprayed grapes of the Soultanina variety. Residues were studied by a simple gas-chromatographic method, using a glass capillary column and NP detector. The decomposition of methamidophos was studied in grapes remaining on the vines after spraying in open and covered vineyards, in grapes harvested and stored in a refrigerated room and in grapes dried into raisins. The recovery of methamidophos was 96.2-112%. The relative standard deviation (RSD) was between 1.4 and 6.2%. The detection limit was 0.02 mg/kg. The results show that, there exists a delayed residue decline during post-harvest storage compared to that for grapes remaining on the vines. From the experimental results, best fit curves were determined and kinetic equations, rate constants and half-lives were calculated. Half-lives found were 16 days for grapes on uncovered vines, 22 days for covered vines and 267 days for grapes stored in a refrigerator. Concentration of methamidophos in raisins was three times higher than that in grapes. © 2004 Elsevier Ltd. All rights reserved. en
heal.journalName Food Chemistry en
dc.identifier.issue 2 en
dc.identifier.volume 91 en
dc.identifier.doi 10.1016/j.foodchem.2003.10.018 en
dc.identifier.spage 235 en
dc.identifier.epage 240 en


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