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Volatility and boiling points of biodiesel from vegetable oils and tallow

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dc.contributor.author Goodrum, JW en
dc.date.accessioned 2014-06-06T06:44:51Z
dc.date.available 2014-06-06T06:44:51Z
dc.date.issued 2002 en
dc.identifier.issn 09619534 en
dc.identifier.uri http://dx.doi.org/10.1016/S0961-9534(01)00074-5 en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/2103
dc.subject Biodiesel en
dc.subject Boiling point en
dc.subject Ethyl ester en
dc.subject Methyl ester en
dc.subject Tallow en
dc.subject TGA en
dc.subject TGA/laser orifice en
dc.subject Vapor pressure en
dc.subject Vegetable oil en
dc.subject.other Esters en
dc.subject.other Fatty acids en
dc.subject.other Quality control en
dc.subject.other Thermogravimetric analysis en
dc.subject.other Vapor pressure en
dc.subject.other Boiling points en
dc.subject.other Vegetable oils en
dc.subject.other vegetable oil en
dc.subject.other Brassica napus var. napus en
dc.subject.other Glycine max en
dc.subject.other Sinapis arvensis en
dc.title Volatility and boiling points of biodiesel from vegetable oils and tallow en
heal.type journalArticle en
heal.identifier.primary 10.1016/S0961-9534(01)00074-5 en
heal.publicationDate 2002 en
heal.abstract Quality control of fuel-related properties of Biodiesel, such as volatility, is needed to obtain consistent engine performance by fuel users. The vapor pressures and boiling points of selected methyl esters and vegetable oils are proposed as quality control metrics for Biodiesel. This type of data was obtained by a rapid new method using thermogravimetric analysis (TGA). One atmosphere boiling points (bps) and temperature-dependent vapor pressures from 1 atm down to 5.332 kPa (40 mmHg) were measured for methyl and ethyl esters of rapeseed oil, canola oil, soybean oil, and tallow. Boiling points (1 atm) ranged from 340°C to 375°C. Methyl and ethyl esters of a given oil differ by ca. 5°C in bps. These results are discussed in terms of the fatty acid composition of the esters and oils. Calibrations showed that the TGA/laser orifice capsule method gave accuracy of ±5%. © 2002 Elsevier Science Ltd. All rights reserved. en
heal.journalName Biomass and Bioenergy en
dc.identifier.issue 3 en
dc.identifier.volume 22 en
dc.identifier.doi 10.1016/S0961-9534(01)00074-5 en
dc.identifier.spage 205 en
dc.identifier.epage 211 en


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