| dc.contributor.author |
Goodrum, JW |
en |
| dc.contributor.author |
Geller, DP |
en |
| dc.date.accessioned |
2014-06-06T06:44:49Z |
|
| dc.date.available |
2014-06-06T06:44:49Z |
|
| dc.date.issued |
2002 |
en |
| dc.identifier.issn |
09608524 |
en |
| dc.identifier.uri |
http://dx.doi.org/10.1016/S0960-8524(02)00006-8 |
en |
| dc.identifier.uri |
http://62.217.125.90/xmlui/handle/123456789/2092 |
|
| dc.subject |
Boiling point |
en |
| dc.subject |
Differential scanning calorimetry (DSC) |
en |
| dc.subject |
Thermogravimetric analysis (TGA) |
en |
| dc.subject |
Triglycerides |
en |
| dc.subject |
Trilaurin |
en |
| dc.subject |
Trimyristin |
en |
| dc.subject |
Tripalmitin |
en |
| dc.subject |
Tristearin |
en |
| dc.subject |
Vapor pressure |
en |
| dc.subject.other |
Biomass |
en |
| dc.subject.other |
Diesel fuels |
en |
| dc.subject.other |
Differential scanning calorimetry |
en |
| dc.subject.other |
Thermogravimetric analysis |
en |
| dc.subject.other |
Vapor pressure |
en |
| dc.subject.other |
Boiling points |
en |
| dc.subject.other |
Biotechnology |
en |
| dc.subject.other |
diesel fuel |
en |
| dc.subject.other |
long chain triacylglycerol |
en |
| dc.subject.other |
medium chain triacylglycerol |
en |
| dc.subject.other |
short chain fatty acid |
en |
| dc.subject.other |
triacylglycerol |
en |
| dc.subject.other |
trilaurin |
en |
| dc.subject.other |
trimyristin |
en |
| dc.subject.other |
tripalmitin |
en |
| dc.subject.other |
tristearin |
en |
| dc.subject.other |
unclassified drug |
en |
| dc.subject.other |
boiling |
en |
| dc.subject.other |
calorimetry |
en |
| dc.subject.other |
diesel |
en |
| dc.subject.other |
fatty acid |
en |
| dc.subject.other |
saturated medium |
en |
| dc.subject.other |
thermogravimetry |
en |
| dc.subject.other |
vapor pressure |
en |
| dc.subject.other |
analytic method |
en |
| dc.subject.other |
article |
en |
| dc.subject.other |
atmospheric pressure |
en |
| dc.subject.other |
biomass |
en |
| dc.subject.other |
boiling point |
en |
| dc.subject.other |
controlled study |
en |
| dc.subject.other |
differential scanning calorimetry |
en |
| dc.subject.other |
intermethod comparison |
en |
| dc.subject.other |
measurement |
en |
| dc.subject.other |
model |
en |
| dc.subject.other |
physical parameters |
en |
| dc.subject.other |
physical phenomena |
en |
| dc.subject.other |
priority journal |
en |
| dc.subject.other |
temperature dependence |
en |
| dc.subject.other |
thermogravimetry |
en |
| dc.subject.other |
vapor pressure |
en |
| dc.subject.other |
volatilization |
en |
| dc.subject.other |
chemistry |
en |
| dc.subject.other |
comparative study |
en |
| dc.subject.other |
evaluation |
en |
| dc.subject.other |
instrumentation |
en |
| dc.subject.other |
methodology |
en |
| dc.subject.other |
pressure |
en |
| dc.subject.other |
sensitivity and specificity |
en |
| dc.subject.other |
statistics |
en |
| dc.subject.other |
temperature |
en |
| dc.subject.other |
validation study |
en |
| dc.subject.other |
Pressure |
en |
| dc.subject.other |
Sensitivity and Specificity |
en |
| dc.subject.other |
Statistics |
en |
| dc.subject.other |
Temperature |
en |
| dc.subject.other |
Thermogravimetry |
en |
| dc.subject.other |
Triglycerides |
en |
| dc.subject.other |
Volatilization |
en |
| dc.title |
Rapid thermogravimetric measurements of boiling points and vapor pressure of saturated medium- and long-chain triglycerides |
en |
| heal.type |
journalArticle |
en |
| heal.identifier.primary |
10.1016/S0960-8524(02)00006-8 |
en |
| heal.publicationDate |
2002 |
en |
| heal.abstract |
In developing compositional models for biomass-based diesel fuel extenders, volatility properties of medium- and long-chain saturated triglycerides are essential to predict the impact of low levels of these compounds in mixtures with short-chain triglycerides. A thermogravimetric analysis (TGA) method for rapid measurement of boiling points and vapor pressure was used to obtain data for four pure medium- and long-chain triglycerides. Normal boiling points at 1 atm and the temperature dependence of vapor pressure from 760 mm down to 25 mm Hg were obtained for trilaurin (C12:0), trimyristin (C14:0), tripalmitin (C16:0), and tristearin (C18:0). The data showed good agreement with the Clausius-Clapeyron model for temperature dependence of vapor pressure up to 1 atm pressure. The results of this study were consistent with those obtained using differential scanning calorimetry (DSC) and with data previously reported for reduced pressure. Copyright © 2002 Elsevier Science Ltd. |
en |
| heal.journalName |
Bioresource Technology |
en |
| dc.identifier.issue |
1 |
en |
| dc.identifier.volume |
84 |
en |
| dc.identifier.doi |
10.1016/S0960-8524(02)00006-8 |
en |
| dc.identifier.spage |
75 |
en |
| dc.identifier.epage |
80 |
en |