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Liquid crystals resulting from combined ionic and hydrogen bonding interactions of nucleobase derivatives

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dc.contributor.author Tsiourvas, D en
dc.contributor.author Mihou, AP en
dc.contributor.author Couladouros, EA en
dc.contributor.author Paleos, CM en
dc.date.accessioned 2014-06-06T06:44:41Z
dc.date.available 2014-06-06T06:44:41Z
dc.date.issued 2001 en
dc.identifier.issn 1058725X en
dc.identifier.uri http://62.217.125.90/xmlui/handle/123456789/2013
dc.relation.uri http://www.scopus.com/inward/record.url?eid=2-s2.0-28544431810&partnerID=40&md5=547d37c6e6ecd8b5bde41e017be26576 en
dc.subject Amphiphilic liquid crystals en
dc.subject Functionalized guanine and cytosine nucleobases en
dc.subject Hydrogen bonding en
dc.subject Molecular recognition en
dc.title Liquid crystals resulting from combined ionic and hydrogen bonding interactions of nucleobase derivatives en
heal.type journalArticle en
heal.publicationDate 2001 en
heal.abstract Salts derived from the interaction of guanine or cytosine acid derivatives with hexadecylamine exhibited smectic liquid crystalline character. This behavior was attributed to a two-level organization process, i.e., to the segregation of lipophilic from hydrophilic moieties due to the formation of the n-alkylammonium salts and to the self-dimerization of these salts through molecular recognition. Furthermore, mixing of the complementary salts in 1:1 molar ratio led, at elevated temperatures, to the formation of their heterodimer which also exhibited a smectic liquid crystalline phase. © 2001 OPA (Overseas Publishers Association) N.V. Published by license under the Gordon and Breach Science Publishers imprint, a member of the Taylor & Francis Group. en
heal.journalName Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals en
dc.identifier.volume 362 en
dc.identifier.spage 177 en
dc.identifier.epage 184 en


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