Transformation of D-glucal to (2S)-hydroxymethyl-dihydropyridones as intermediates to piperidine alkaloids

dc.contributor.author	Koulocheri, SD	en
dc.contributor.author	Haroutounian, SA	en
dc.date.accessioned	2014-06-06T06:44:00Z
dc.date.available	2014-06-06T06:44:00Z
dc.date.issued	1999	en
dc.identifier.issn	00397881	en
dc.identifier.uri	http://62.217.125.90/xmlui/handle/123456789/1616
dc.relation.uri	http://www.scopus.com/inward/record.url?eid=2-s2.0-0032746859&partnerID=40&md5=a1ea7759dac714927ef00cc240cf0e89	en
dc.subject	Asymmetric synthesis	en
dc.subject	D-glucal	en
dc.subject	Dihydropyridone	en
dc.subject	Piperidine alkaloids	en
dc.subject.other	gluconate calcium	en
dc.subject.other	piperidine derivative	en
dc.subject.other	pyridone derivative	en
dc.subject.other	article	en
dc.subject.other	chemical reaction	en
dc.subject.other	chemical structure	en
dc.subject.other	chirality	en
dc.subject.other	reaction analysis	en
dc.subject.other	synthesis	en
dc.title	Transformation of D-glucal to (2S)-hydroxymethyl-dihydropyridones as intermediates to piperidine alkaloids	en
heal.type	journalArticle	en
heal.publicationDate	1999	en
heal.abstract	The efficient transformation of D-glucal to (2S)-hydroxymethyl- dihydropyridone 1 in five steps and 61% overall yield is reported. The latter is used as chiral building block for the synthesis of piperidine alkaloids. The preparation of piperidinol 8, which may be elaborated to the synthesis of (-)-desoxoprosophylline 9, is also presented.	en
heal.journalName	Synthesis	en
dc.identifier.issue	11	en
dc.identifier.spage	1889	en
dc.identifier.epage	1892	en